Welcome to Smogon! Take a moment to read the Introduction to Smogon for a run-down on everything Smogon, and make sure you take some time to read the global rules.
I already have plans for Wednesday and Thursday nights... I could mainly play mornings (Tuesday-Thursday (maybe Friday? not sure) from 10am to 1pm), but I could also play some afternoons (Tuesday-Thursday 3pm to 5pm). The only night I could play (but I would need to ask for it) is Sunday.