Welcome to Smogon! Take a moment to read the Introduction to Smogon for a run-down on everything Smogon, and make sure you take some time to read the global rules.
My time, I can do Monday/Wednesday 7 am - 1 pm and 2:15 - 5:30 pm, Tuesday 11 am -12:30 pm and 3:30 - 5:30 pm, Thursday 11 am - 12:30 pm and 2:45 - 5:30 pm, and Friday 7 am - 1 pm and 2:15 - 5:30 pm, with 7:15 - 11 pm on Friday a weak maybe if it is the only time.